Rh2(esp)2-catalyzed allylic and benzylic oxidations.
نویسندگان
چکیده
The dirhodium(II) catalyst Rh2(esp)2 allows direct solvent-free allylic and benzylic oxidations by T-HYDRO with a remarkably low catalyst loading. This method is operationally simple and scalable at ambient temperature without the use of any additives. The high catalyst stability in these reactions may be attributed to a dirhodium(II,II) catalyst resting state, which is less prone to decomposition.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 27 شماره
صفحات -
تاریخ انتشار 2015